Exercise E6 Efficiency
(written test, approx. 14 % of a 60-minute written test, SS2023)
A lithium-ion battery cell can be considered a linear voltage source with an internal resistance $R_\rm i$ and a source voltage $U_\rm s=3.5 ~\rm V$. The battery shall provide energy for a mobile device with a load resistance of $R_\rm L=2 ~\Omega$ The following values are from the lithium-ion battery datasheet:
- Internal impedance: $R_\rm i =50 ~\rm m\Omega$
- Maximum discharge current: $I_{\rm Dis max} =3 ~\rm A$
- Typical capacity: $2'600 ~\rm mAh$
1. Draw an equivalent circuit diagram with the internal resistance and an external load. Label all voltages and currents.
2. Calculate the efficiency of the battery in this case.
3. (HARD) Once the load resistance is changed, the efficiency for discharging also changes. What would be the lowest possible efficiency?
Lowest efficiency for highest current, so for $I_{\rm Dis max}. In this case, the efficiency is:
\begin{align*} \eta &= {{U_\rm S - R_\rm i \cdot I_{\rm Dis max}}\over{U_\rm S}} \\ &= 1 - R_\rm i \cdot {{I_{\rm Dis max}}\over{U_\rm S}} \\ &= 1 - 0.05 {~\rm \Omega} \cdot {{3~\rm A}\over{3.5 ~\rm V}} \\ \end{align*}
4. Calculate the voltage drop on the load resistance $R_\rm L=2 ~\Omega$.
\begin{align*} U_\rm L= U_\rm S \cdot {{R_\rm L}\over{R_\rm L + R_\rm i}} \end{align*}
5. How much charged $\rm Li$ ions have to be moved in the battery to charge it from $0~ \%$ to $100~\%$?
Lithium is monovalent – so, there are only $\rm Li^+$ ions. The elementary charge is $q_\rm e=1.602 \cdot 10^{-19} ~\rm C$.